The amsmath package provides the align environment for aligning multiple equations at a common point (typically the = sign). Use & to mark the alignment point.
The align environment
LaTeX
\begin{align}
x + y &= 5 \\
2x - y &= 1
\end{align}
% Sans numérotation : align*
\begin{align*}
(a + b)^2 &= a^2 + 2ab + b^2 \\
(a - b)^2 &= a^2 - 2ab + b^2
\end{align*}
Multi-line calculation
To develop a calculation step by step, align on the = sign:
LaTeX
\begin{align*}
f(x) &= (x+1)(x-2) \\
&= x^2 - 2x + x - 2 \\
&= x^2 - x - 2
\end{align*}
Centered equations with gather
If you simply want to center multiple equations without aligning them, use gather:
LaTeX
\begin{gather*}
E = mc^2 \\
F = ma \\
PV = nRT
\end{gather*}
Warning
Do not use
eqnarray, which is obsolete. Always prefer align from the amsmath package, which handles spacing better.